TRIPLE PHOTOIONIZATION OF LITHIUM: A FUNDAMENTAL PROCESS R. Wehlitz,$^*$ M.-T. Huang,$^*$ B. D. DePaola,$^{\#}$ J. C. Levin,$^{\dag}$ I. A. Sellin,$^{\dag}$ T. Nagata,$^{\ddag}$ J. W. Cooper,$^{\P}$ and Y. Azuma$^*$ $^*$ Photon Factory, IMSS, KEK, Tsukuba, Ibaraki 305-0801, Japan $^{\#}$Dept. of Physics, Kansas State University, Manhatten, KS 66506, USA $^{\dag}$Dept. of Physics, University of Tennessee, Knoxville, TN 37996, USA $^{\ddag}$Meisei University, Hodokubo, Hino, Tokyo 191, Japan $^{\P}$IPST, University of Maryland, College Park, Maryland 20472, USA We present the triple photoionization cross-section of Li from threshold up to 424eV. Of particular interest is the threshold region where the motion of three escaping electrons is highly correlated. The cross-sections observed are compatible with the existence of two threshold laws which are both power laws with different exponents and are valid in different energies ranges.