CROSS-CORRELATION TOF METHOD BY PSUDORANDOM PULSE DISCHARGE Hisashi Kawaguchi, Masanori Yamato, Hiroshi Ohoyama, and Toshio Kasai Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 Japan A new cross-correlation time-of-flight (CC-TOF) method for pulsed metastabl e atom beam is demonstrated. In this method, we modulate the grid voltage for the metastable atom formation with pseudorandom pulse sequence instead of mechanical chopping. The TOF spectrum convoluted from the observed CC-TOF spectrum is found to nicely reproduce the conventional TOF spectrum, indicating useful applicability of the new method.